Acrylamide Copolymerized Low Formaldehyde thermosetting Resin for Particle Board
DOI:
https://doi.org/10.36808/if/2025/v151i9/170553Keywords:
Acrylamide, UF resin, FTIR, Formaldehyde emission, Bending strength etc.Abstract
The decrease of formaldehyde emission in wood panel products is crucial, and it can be partially managed by modifying the resin. The perforator method (IS 13745:1993) was used to test the effectiveness of adding acrylamide (1.5 to 3.5%) to reduce formaldehyde emission from wood particle board. The functional groups of the produced control UF resin, mechanically modified acrylamide urea formaldehyde resin (AUF) and during reaction modified acrylamide urea formaldehyde resin (UFA) were identified by Fourier Transform Infra-red (FTIR). Indian standard 3087:2005 has been used for determination of physical and mechanical characteristics. The results show that the static bending modulus of rupture (MOR) of the manufacture boards ranged from 20.89 to 29.32 N/mm2 of, and the modulus of elasticity (MOE) from 2986 to 3678 N/mm2, while internal bond strength (IB) ranged from 0.43 to 0.52 N/mm2. As per the requirements of IS 3087 (2005), 1.5% mechanically modified urea formaldehyde and 2.5% internally modified urea formaldehyde based agro composites yielded the best results for grade II particle boards with respect to static bending strength. From the studies, it was found that acrylamide addition (1.5% mechanically and 2.5% internally) reduces the formaldehyde emission content in the panel without affecting the mechanical qualities.
References
Abdullah Z.A. and Byung-Dae D.P. (2009). Hydrolytic stability of cured formaldehyde resins modified by additives, Journal of Applied Polymer Science, 114(2): 1011-1017. http://dx.doi.org/ 10.1002/app.30713.
Abdullah Z.A. and Byung-Dae D.P. (2010). Influence of acrylamide copolymerization of urea formaldehyde resins adhesives to their chemical structure and performance, Journal of Applied Polymer Science, 117: 3181-3186. https://doi.org/ 10.1002/APP.32237.
Abdullah Z.A. and Yunus A.Y.M. (2019). Analysis of urea formaldehyde and urea formaldehyde acrylamide resins using thermogrametric method, Journal of Science and Technlogy, 2(1): 1-8.
Ayaz E.A., Durkan R. and Bagis B. (2013). The effect of acrylamide incorporation on thermal and physical properties of denture resins, Journal of Advanced Prosthodontics, 5: 110117. https://doi.org/10.4047/jap.2013.5.2.110.
Basta A.H., EI-Saied H., Jerrold E. and Sabo R. (2011). Performed Amide containing biopolymers for improving the environmental performance of synthesized urea formaldehyde in agro fiber composites, Journal of Polymer and the Environment, 19(2): 405-412. https://doi.org/10.1007/s10924011-0286-4.
Byung D.P., Ho-Won J. and Sang-Min L. (2010). Modification of UF resin adhesives by acrylamide coplymerization for low formaldehyde emission, 64th International conention Madison, WI.
Dukarska D. and Łecka J. (2006). Optimization of the process of pressing particleboards by means of modifying phenolformaldehyde resin with amide polymers, Holz als Roh- und Werkstoff, 64: 403–409. DOI 10.1007/s00107-005-0093-5.
EI-Naggar A.M., Kandeel K.A., Khafaga M.R. and Zabran A.H. (2001). Control of resin release from particle board by gamma irradiation 1. Thermal decomposition behaviour and structural morphology, Journal of Applied Polymer Science, 82: 28692881. https://doi.org/10.1002/app.2143.
George G.A. (1982). Method of reducing formaldehyde emission from formaldehyde condensation polymers. United State Patent, 4, 346, 181.
Indian Standard 13745 (2020). Method for determination of Formaldehyde content in particle board by extraction method called perforator method, Bureau of Indian Standard, New Delhi.
Indian Standard 3087 (2005). Partical boards of wood and other lingnocellulosic materials (medium density) for general purposes, Bureau of Indian Standard, New Delhi.
İstek A., Özlüsoylu İ., Çelik S. and Gönül Ş. (2017). Ahşap Esaslı Levha Sektöründe Kullanılan Yanma Geciktiriciler. İleri Teknoloji Bilimleri Dergisi, 6(3), 389-399.
Kim G.M. (2001). Examination of selected synthesis parameters for woodadhesive type urea formaldehyde resin by CNMR Spectroscopy, Journal of Applied Polymer Science, 80: 2800-2814. doI: https://doi.org/10.1002/%28SICI% 2910990518%2819990401%2937%3A7%3C995%3A%3AAI D-POLA14%3E3.0.CO%3B2-6.
Nakason C., Kaesman A., Rungvichaniwat A., Homsin K. and Kiatkanjonwong S. (2001). Rheological and curing behaviour of reactive blending 1. Maleated Natural Ribber- Cassava starch, Journal of Applied Polymer Science, 81: 2803-2813. http://dx.doi.org/10.1002/app.12191.
Osemeahon S.A. and Barminas J.T. (2006.) Properties of a low viscosity urea formaldehyde resin prepared through a new synthetic route, Bullietin Pure Applied Science, 25 C: 67-76.
Pizzi A. (1994). Advanced wood adhesives technology (New York: Marcel Dekker Inc), 289 pp.
Pizzi A., Beaujean M., Zhao C., Properz M. and Huang Z. (2001) Acetal- introduced strength increases and lower resin content of MUF and other polycondensate adhesives, Journal of Applied Science, 84: 2561-2571. http://dx.doi.org/10.1002/ app.11105.
Que Z., Furuno T., Katoh S. and Nishino Y. (2007). Evaluation of three test methods in determination of formaldehyde emission from particle board bonded with different mole ratio in the urea formaldehyde resin, Building and Enviornment, 42(3): 12421249. http://dx.doi.org/10.1016/j.buildenv.2005.11.026.
Rammon R.M. (1984). The influence of synthesis parameters on the structure of urea formaldehyde, Washington State University, 208 pp.
Razali N.S., Hazan N.A.M. and Noh I.A. (2012). Manufacturing of particle board from oil palm frond. Final year project report, Diploma in wood industry, faculty of applied science- Universiti Tecknologi MARA.
Ren X., Li C. and Li K. (2013). Investigation of acrylamidemodified melamine formaldehyde resins as a compatibilizer for Kenaf- unsaturated polyester composites, Polymer Engineering and Science, 53: 8. http://dx.doi.org/10.1002/pen.23418.
Robert P. Avis (1973). Glyoxal- acrylamide formaldehyde urea wet strength resin, United State Patent, 3, 773, 612.
Wang W., Seen Y., Kong F., Yang G. and Fatchi P. (2016). Preparation and characterization of lignin acrylamide copolymers as a paper strength additive, Bioresourecs, 11(1): 1765-1783. http://dx.doi.org/10.15376/biores.11.1.1765-1783.
Downloads
Downloads
Published
How to Cite
Issue
Section
License
Unless otherwise stated, copyright or similar rights in all materials presented on the site, including graphical images, are owned by Indian Forester.